COBALT(II) AND COBALT(III) COMPLEXES OF A NOVEL HOMOLEPTIC THIOETHER CAGE

被引：32

作者：

OSVATH, P ^{[1
]}

SARGESON, AM ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA, DEPT PHYS & INORGAN CHEM, NEDLANDS, WA 6009, AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 15期

关键词：

D O I：

10.1039/c39910001036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low-spin hexadentate cobalt(II) and cobalt(III) complexes of the hexathioether cage (1,8-dimethyl-3,6,10,13,16,19-hexathiabicyclo[6.6.6]icosane) have been synthesised, their redox and spectral properties have been investigated, and the encapsulation of the cobalt(II) ion has been established by an X-ray crystal structure determination, which shows the metal ion to be coordinated to six thioether sulphur atoms at distances ranging from 2.265(3) to 2.354(2) angstrom.

引用

页码：1036 / 1038

页数：3

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