THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE CATALYZED BY NICKEL-COMPLEXES

被引：10

作者：

CHEONG, M ^{[1
]}

LEE, SH ^{[1
]}

SA, YS ^{[1
]}

LEE, JS ^{[1
]}

KIM, YG ^{[1
]}

机构：

[1] POHANG INST SCI & TECHNOL,DEPT CHEM ENGN,POHANG,SOUTH KOREA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 68卷 / 03期

关键词：

D O I：

10.1016/0304-5102(91)80086-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly efficient catalyst system consisting of a nickel complex, a trialkylamine, and a tetraaklyltin was studied for the isomerization of methyl formate to acetic acid. The effects of temperature, solvent, methyl formate concentration and CO partial pressure on the rate and selectivity of the reaction were investigated. The role of promoter tetraalkyltin as a Lewis acid and synergistic effects between promoters are explained using a proposed mechanism.

引用

页码：277 / 288

页数：12

共 43 条

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