学术探索
学术期刊
新闻热点
数据分析
智能评审

ELECTROPHILIC SUBSTITUTION AT AN OLEFINIC CARBON-ATOM - SOME STUDIES OF THE MECHANISM OF THE TRIFLUOROACETYLATION OF ARYL VINYL SULFIDES

被引：21
作者：
HOJO, M
MASUDA, R
KAMITORI, Y
OKADA, E
机构：
[1] Department of Industrial Chemistry, Faculty of Engineering, Kobe University
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 06期
关键词：
D O I：
10.1021/jo00006a001
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A study of the mechanism of the trifluoroacetylation of aryl vinyl sulfides was made. The rates of trifluoroacetylation of ArSCH = CH2, ArSCH = CD2, cis-ArSCH = CHD, and trans-ArSCH = CHD were determined. The results imply that this electrophilic substitution reaction proceeds by a single-step mechanism.
引用
收藏
页码：1975 / 1976
页数：2
相关论文
共 13 条
[1]  
ALDER RW, 1971, MECHANISM ORGANIC CH, P286
[2]  
HINE J, 1962, PHYSICAL ORGANIC CHE, P352
[3]  
HOJO M, 1990, SYNTHESIS-STUTTGART, P425
[4]   NEW REACTION OF TRITHIOORTHOACETATES - REACTION WITH ACYLATING REAGENTS [J].
HOJO, M ;
MASUDA, R .
JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (07) :963-965
[5]  
HOJO M, 1989, SYNTHESIS-STUTTGART, P215
[6]  
HOJO M, 1986, SYNTHESIS-STUTTGART, P1016
[7]   ELECTROPHILIC SUBSTITUTIONS OF OLEFINIC HYDROGENS .2. ACYLATION OF VINYL ETHERS AND N-VINYL AMIDES [J].
HOJO, M ;
MASUDA, R ;
KOKURYO, Y ;
SHIODA, H ;
MATSUO, S .
CHEMISTRY LETTERS, 1976, (05) :499-502
[8]   NUCLEOPHILIC NITROGEN-NITROGEN EXCHANGE-REACTION AT AROMATIC CARBON-ATOMS - REACTION OF N,N-DIMETHYL-2,4-BISTRIFLUOROACETYL-1-NAPHTHYLAMINE WITH VARIOUS AMINES [J].
HOJO, M ;
MASUDA, R ;
OKADA, E .
TETRAHEDRON LETTERS, 1987, 28 (49) :6199-6200
[9]  
HOJO M, 1978, SYNTHESIS-STUTTGART, P284
[10]  
HOJO M, 1990, SYNTHESIS-STUTTGART, P347
12