SYNTHESIS AND CONVERSIONS OF METALLOCYCLES .7. A NOVEL-APPROACH TO THE SYNTHESIS OF 3,4-DIALKYL-SUBSTITUTED ALUMINACYCLOPENTANES IN THE PRESENCE OF CP2ZRCL2

被引：17

作者：

DZHEMILEV, UM

IBRAGIMOV, AG

MOROZOV, AB

MUSLUKHOV, RR

TOLSTIKOV, GA

机构：

[1] Institute of Chemistry, Bashkir Scientific Center, Ural Branch, Academy of Sciences of the USSR, Ufa

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 07期

关键词：

D O I：

10.1007/BF00961245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel approach was developed for the stereoselective synthesis of trans-3,4-dialkyl-substituted aluminacyclopentanes from alpha-olefins, metallic magnesium, and EtAlCl2 in the presence of catalytic amounts of CP2ZrCl2. The hydrolysis and deuterolysis products of the 3,4-dialkyl-substituted aluminacyclopentanes obtained are only in the trans configuration.

引用

页码：1425 / 1427

页数：3