EXCITATION PROFILES VERSUS POTENTIAL PROFILES IN THE DETERMINATION OF THE CHARGE-TRANSFER CONTRIBUTION TO SERS OF PYRIDINE ON A SILVER ELECTRODE

被引：13

作者：

KUDELSKI, A ^{[1
]}

BUKOWSKA, J ^{[1
]}

机构：

[1] UNIV WARSAW,DEPT CHEM,PL-02093 WARSAW,POLAND

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1995年 / 26卷 / 10期

关键词：

D O I：

10.1002/jrs.1250261005

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The relative SERS enhancement factors for pyridine adsorbed on a silver electrode were determined as a function of the laser wavelength and applied potential. The charge-transfer (CT) contribution to the SERS intensity (I), G(CT), was estimated from the excitation profiles (I vs. kv) and compared with the G(CT) values previously obtained from the I vs. electrode potential curves. A critical discussion of the determination of G(CT) with the aid of both methods is given.

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页码：955 / 958

页数：4

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