BAEYER-VILLIGER OXIDATION OF ALKYL OXOCYCLOHEXANECARBOXYLATES

被引：14

作者：

HUBERT, AJ

STARCHER, PS

机构：

[1] Union Carbide Corporation, Technical Centre, South Charleston, WV 25303

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 20期

关键词：

D O I：

10.1039/j39680002500

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Baeyer-Villiger oxidation of methyl 3- and 4-oxocyclohexanecarboxylates gave the expected hexanolides, whereas ethyl 2-oxocyclohexanecarboxylate(I) gave 5-ethoxyoxalylpentanoic acid by way of ethyl 1-hydroxy-2- oxocyclohexanecarboxylate, formed by epoxidation of the enol form of (I).

引用

页码：2500 / &

共 11 条

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