XPS STUDY OF THE CARBON-FIBER MATRIX INTERFACE

被引：124

作者：

NAKAYAMA, Y

SOEDA, F

ISHITANI, A

机构：

[1] Toray Research Center, Inc., Otsu, Shiga, 520, 1-1-1, Sonoyama

来源：

CARBON | 1990年 / 28卷 / 01期

关键词：

carbon fiber; chemical modification; composite; ESCA; interface; XPS;

D O I：

10.1016/0008-6223(90)90088-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray Photoelectron Spectroscopy (XPS) combined with gas phase chemical modification was applied to study the variation of the carbon structure and quantity of functional groups introduced by oxidation of a carbon fiber surface. The amount of functional groups effective for adhesion of the matrix at the interface was correlated to the fractional coverage of an epoxide on the fiber surface using a liquid phase chemical modification process. A mechanism for adhesion was proposed. © 1990.

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页码：21 / 26

页数：6

相关论文

共 16 条

[1] HIGH ENERGY PHOTOELECTRON SPECTROSCOPIC STUDY OF CARBON FIBRE SURFACES [J].

BARBER, M ;

SWIFT, P ;

EVANS, EL ;

THOMAS, JM .

NATURE, 1970, 227 (5263) :1131-&

[2] SURFACE TREATMENTS OF CARBON-FIBERS STUDIES BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

BREWIS, DM ;

COMYN, J ;

FOWLER, JR ;

BRIGGS, D ;

GIBSON, VA .

FIBRE SCIENCE & TECHNOLOGY, 1979, 12 (01) :41-52

[3]

DEVILBISS TA, 1986, COMPOSITE INTERFACES, P307

[4] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .6. PILOT-PLANT SURFACE-TREATMENT AND EPOXY-RESIN COMPOSITES [J].

HARVEY, J ;

KOZLOWSKI, C ;

SHERWOOD, PMA .

JOURNAL OF MATERIALS SCIENCE, 1987, 22 (05) :1585-1596

[5] ESCA STUDIES OF STRUCTURAL-CHANGES OF POLY(ACRYLONITRILE) AND POLY(CHLOROACRYLONITRILE) - HIGH-TEMPERATURE-INDUCED, ELECTRON-IMPACT-INDUCED, AND ULTRAVIOLET-LIGHT-INDUCED CHANGES [J].

HIRAOKA, H ;

LEE, WY .

MACROMOLECULES, 1978, 11 (03) :622-624

[6] SURFACE STUDY OF CARBON-FIBERS WITH ESCA AND AUGER-ELECTRON SPECTROSCOPY [J].

HOPFGARTEN, F .

FIBRE SCIENCE & TECHNOLOGY, 1978, 11 (01) :67-79

[7] APPLICATION OF X-RAY PHOTOELECTRON-SPECTROSCOPY TO SURFACE-ANALYSIS OF CARBON-FIBER [J].

ISHITANI, A .

CARBON, 1981, 19 (04) :269-275

[8] XPS ANALYSIS OF NH3 PLASMA-TREATED POLYSTYRENE FILMS UTILIZING GAS-PHASE CHEMICAL MODIFICATION [J].

NAKAYAMA, Y ;

TAKAHAGI, T ;

SOEDA, F ;

HATADA, K ;

NAGAOKA, S ;

SUZUKI, J ;

ISHITANI, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1988, 26 (02) :559-572

[9] XPS STUDY OF ORIENTED ORGANIC-MOLECULES - VESICLES OF AZOBENZENE-CONTAINING ALKYL AMMONIUM AMPHIPHILES [J].

NAKAYAMA, Y ;

TAKAHAGI, T ;

SOEDA, F ;

ISHITANI, A ;

SHIMOMURA, M ;

KUNITAKE, T .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1988, 122 (02) :464-474

[10] INFLUENCE OF CRYSTALLINE PERFECTION AND SURFACE SPECIES ON THE X-RAY PHOTOELECTRON-SPECTRA OF NATURAL AND SYNTHETIC GRAPHITES [J].

SCHLOGL, R ;

BOEHM, HP .

CARBON, 1983, 21 (04) :345-358