SYNTHESIS OF 3'-DEOXYADENOSINE-3'-SPIROCYCLOPROPANE, 3'-DEOXYURIDINE-3'-SPIROCYCLOPROPANE, AND 5'-DEOXY-4',5'-METHANOADENOSINE

被引：22

作者：

SAMANO, V ^{[1
]}

ROBINS, MJ ^{[1
]}

机构：

[1] BRIGHAM YOUNG UNIV,DEPT CHEM,PROVO,UT 84602

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)73206-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cycloaddition of diazomethane with 3'-deoxy-3'-methylene- and 4',5'-didehydro-5'-deoxynucleoside derivatives followed by sensitized photochemical extrusion of nitrogen provided the previously unreported 3'- and 4'-spirocyclopropane nucleoside derivatives. Enhancement of the cycloaddition reactions by electron withdrawing benzoyl protecting groups was observed.

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页码：3445 / 3448

页数：4

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