COMPOSITION AND STRUCTURE OF THE ANODIC FILMS ON TITANIUM IN AQUEOUS-SOLUTIONS

被引:89
作者
PANKUCH, M
BELL, R
MELENDRES, CA
机构
[1] ARGONNE NATL LAB,DIV MAT SCI,ARGONNE,IL 60439
[2] ARGONNE NATL LAB,DIV CHEM TECHNOL,ARGONNE,IL 60439
关键词
RAMAN SPECTROSCOPY; TITANIUM OXIDE FILM; ANODIC FILMS ON TITANIUM; COMPOSITION; STRUCTURE;
D O I
10.1016/0013-4686(93)85098-J
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Surface-enhanced Raman spectra of the amorphous him on titanium have been obtained for the first time. The anodic corrosion him at low potentials is identified to be highly disordered TiO2 with some Ti2O3 also present. The presence of the anatase and rutile modifications of TiO2 at high voltages (greater than or equal to 80 V) is confirmed.
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页码:2777 / 2779
页数:3
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