SEMICLASSICAL PROPAGATION - PHASE INDEXES AND THE INITIAL-VALUE FORMALISM

被引:126
作者
CAMPOLIETI, G
BRUMER, P
机构
[1] Chemical Physics Theory Group, Department of Chemistry, University of Toronto, Toronto
来源
PHYSICAL REVIEW A | 1994年 / 50卷 / 02期
关键词
D O I
10.1103/PhysRevA.50.997
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Initial-value phase-space integral representations for a time-dependent propagator are obtained in the coordinate and momentum representations. To do so we first derive nonuniform semiclassical propagators for the various representations, obtaining the global-time semiclassical phase indices (Maslov indices) due to caustics. Results include readily implementable general phase index formulas for any type of caustic, including cases where the Morse index theorem is inapplicable. The method of obtaining the indices is general and based simply on concatenating uniform short-time propagators which also gives rise to alternative path-integral forms. Initial-value integral representations are then derived by introducing a method of extending short-time initial-value propagator formulas to global times via a simple stationary-phase asymptotic-equivalence approach. The integrals reduce to the nonuniform semiclassical propagators within the stationary-phase approximation, are uniform about caustics, and have integrand phases which properly account for the global-time phases in terms of appropriate Maslov indices. The initial-value integrals are also consistently derived via a canonical mapping procedure on the coordinate-space path integral. Initial-value integrals for time-dependent wave-function propagation are also given. Evaluation of the initial-value integral expressions do not require trajectory root searches for propagation.
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页码:997 / 1018
页数:22
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