NEW FLUORINE-CONTAINING BUILDING-BLOCKS FROM TRIFLUOROETHANOL .1.

被引：56

作者：

PATEL, ST ^{[1
]}

PERCY, JM ^{[1
]}

WILKES, RD ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

TETRAHEDRON | 1995年 / 51卷 / 33期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0040-4020(95)00525-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new fluorine containing acyl anion equivalent 1,1-difluoro-2-lithio-2-[(methoxyethoxy)methoxy]ethene 12 has been prepared from trifluoroethanol and trapped with a number of electrophiles in good yield. Effective electrophiles included Group(IV) halides and carbonyl compounds. Attempts to alkylate using iodomethane were unsuccessful.

引用

页码：9201 / 9216

页数：16

共 49 条

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