ELECTROCHEMISTRY OF ORGANOPHOSPHORUS COMPOUNDS .2. ELECTROREDUCTION OF TRIPHENYLPHOSPHINE AND TRIPHENYLPHOSPHINE OXIDE

被引：63

作者：

SANTHANAM, KS

BARD, AJ

机构：

[1] Department of Chemistry, University of Texas, Austin

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 05期

关键词：

D O I：

10.1021/ja01007a005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical reduction of triphenylphosphine (TPP) and triphenylphosphine oxide (TPPO) has been investigated using polarography, cyclic voltammetry, coulometry, and product analysis. The reduction of TPP proceeds by a one-electron transfer to form the anion radical which undergoes cleavage of a phenyl group. © 1968, American Chemical Society. All rights reserved.

引用

页码：1118 / +

页数：1

共 17 条

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