LEWIS-BASE ADDUCTS OF GROUPS-II METAL(I) COMPOUNDS .62. THE CRYSTAL-STRUCTURES OF THE 1-1 ADDUCTS OF COPPER(I) CHLORIDE, BROMIDE AND THIOCYANATE WITH QUINOLINE

被引：31

作者：

HEALY, PC ^{[1
]}

SKELTON, BW ^{[1
]}

WATERS, AF ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 08期

关键词：

D O I：

10.1071/CH9911049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adducts (1:1) of copper(I) chloride, bromide and thiocyanate with quinoline have been synthesized and have been the subject of single-crystal X-ray structure determinations at 295 K. Crystals of the chloride are orthorhombic, P2(1)2(1)2(1), a 15.358(7), b 14.309(6), c 3.801(2) angstrom, Z 4; R was 0.055 for 541 'observed' reflections. Crystals of the bromide are monoclinic, C2/c, a 19.417(5), b 14.048(4), c 15.753(6) angstrom, beta 125.31(2)-degrees, Z 4 tetramers; R was 0.049 for 1138 'observed' reflections. Crystals of the thiocyanate are monoclinic, P2(1)/c, a 5.682(1), b 10.412(2), c 16.838(5) angstrom, beta 97.48(2)-degrees, Z 4 f.u.; R was 0.045 for 914 'observed' reflections. The chloride takes the form of the common 'stair' polymer, unexpectedly, while the thiocyanate is an expanded version of the same. The bromide provides a second example of a novel tetrameric 'basket' structure exemplified previously by the iodide analogue.

引用

页码：1049 / 1059

页数：11

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