EXAFS IN DISPERSIVE MODE, A NEW TOOL FOR STUDYING IN SITU KINETICS: EXAMPLE OF ELECTROCHEMICAL INCLUSION OF COPPER SPECIES IN AN ORGANIC CONDUCTOR

被引：4

作者：

Dartyge, E. ^{[1
]}

Fontaine, A. ^{[1
]}

Tourillon, G. ^{[1
]}

Jucha, A. ^{[1
]}

机构：

[1] LURE, Lab CNRS, CEA, MEN, F-91405 Orsay, France

来源：

JOURNAL DE PHYSIQUE | 1986年 / 47卷 / C-8期

关键词：

D O I：

10.1051/jphyscol:19868114

中图分类号：

学科分类号：

摘要：

The mechanisms and the kinetics for the electrochemical inclusion 01 copper species inside poly 3methylthiophene (an organic conducting polymer) have been studied in situ by dispersive x ray absorption spectroscopy. The EXAFS results complement the three chemical steps previously deduced from XANES and the nature of chemical bonds formec during the inclusions processes are then precised : - a fast Cu2+ -> Cu1+ reduction where the Cu1+ ions are complexed by the 0 atoms coming from the dopant used during the polymer synthesis (SO3CF3)(-) -Fixation of the new synthetized Cu(1+)ions on the S atoms of poly 3methylthiophene - Growing of (111) metallic copper platelets.

引用

页码：91 / 98

页数：8