EXCHANGE IN ALKYLZINC ALKOXIDES AND ALKYLCADMIUM ALKOXIDES

被引：20

作者：

JEFFERY, EA

MOLE, T

机构：

[1] Division of Applied Chemistry, CSIRO Chemical Research Laboratories, Melbourne, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1968年 / 21卷 / 05期

关键词：

D O I：

10.1071/CH9681187

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coupling of111Cd and113Cd to both the methyl and alkoxyl protons has been observed in the proton magnetic resonance spectra of methylcadmium alkoxides. P.m.r. spectrometry has also been used to investigate the exchange reactions of methylcadmium and alkylzinc alkoxides. In particular exchanges between Me2Cd and MeCdOR (R = Me, Et, Pr1, and Ph), between R2Zn and RznOR′ (R = Me, Et; R′ = Me, Et, Pr1, and But), and between Me3Al and MeZnOR′ (R′ = Et, Prt, and But), have been examined. © 1968 CSIRO. All rights reserved.

引用

页码：1187 / &

共 19 条

[1] ORGANOMETALLIC COMPOUNDS .3. ACIDOLYSIS OF SOME SYMMETRICAL AND UNSYMMETRICAL-DIAIKYLZINCS BY PRIMARY AMINES [J].