KINETICS OF NITRIC ACID OXIDATION OF SUBSTITUTED DIPHENYLMETHANES

被引：2

作者：

OGATA, Y

TEZUKA, H

KAMEI, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya

来源：

TETRAHEDRON | 1969年 / 25卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)83033-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The nitric acid oxidation of substituted diphenylmethanes has been kinetically studied in 70 vol % aqueous acetic acid and in 60 vol % aqueous dioxan at 90°. The Hammett's plot for the substituent effect correlates to σ+ rather than σ, giving a negative ρ{variant}-value of -1·7 in 70 vol % aqueous acetic acid and -1·2 in 60 vol % aqueous dioxan. © 1969.

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页码：4919 / &

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