METAL-COMPLEXES OF FUNCTIONALIZED PHOSPHINES .1. SYNTHESIS AND CHARACTERIZATION OF 2-DIPHENYLPHOSPHINOETHYLAMINES AND SOME OF THEIR COMPLEXES WITH PLATINUM - X-RAY STRUCTURE OF [PT(PH2PCH2CH2NHBU(TERT))(PH2PCH2CH2NHBU(TERT).HCL)CL]CL.H2O

被引：17

作者：

BASSETT, M ^{[1
]}

DAVIES, DL ^{[1
]}

NEILD, J ^{[1
]}

PROUSE, LJS ^{[1
]}

RUSSELL, DR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 4-5期

关键词：

D O I：

10.1016/S0277-5387(00)80220-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new bidentate ligands Ph2PCH2CH2NHR [R = Bu(t), CH2Ph, CH(Me) Ph] and Ph2PCH2CH2N(CH2Ph)2 and their corresponding hydrochloride salts have been synthesized and were characterized by H-1, P-31-{H-1} and C-13-{H-1} NMR spectroscopy. The ligand Ph2PCH2CH2NHBu(t) reacts with K2PtCl4 or (COD)PtCl2 to form [P activated t(Ph2PCH2CH2NHBu(t))(Ph2PCH2CH2NHBu(t).HCl)Cl]Cl whose structure has been determined by X-ray diffraction. Treatment of this complex with HCl gas gives [Pt(Ph2PCH2CH2NHBu(t).HCl)2Cl2] which can also be synthesized from Ph2PCH2CH2NHBu(t).HCl and K2PtCl4.

引用

页码：501 / 507

页数：7

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