PYROLYTIC CHEMISTRY OF BENZYL BENZOATE

被引：5

作者：

CHEN, PS

CHOU, CH

机构：

[1] Department of Chemistry, National Sun Yat-Sen University, Kaohsiung

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1994年 / 41卷 / 05期

关键词：

FURFURYL BENZOATE; BENZYL BENZOATE; FLASH VACUUM PYROLYSIS;

D O I：

10.1002/jccs.199400080

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flash vacuum pyrolysis of benzyl benzoate (3) at temperatures in the range 750-900 degrees C and at 10(-2) torr gave diphenylmethane (5) as the major product with toluene (6) and eight other trace products, namely biphenyl (7), dibenzyl (8), 2-, 3-, 4-phenyltoluenes (9, 10, 11, respectively), fluorene (12), benzyl alcohol (4) and benzaldehyde (13). The mechanism of formation of these products is proposed to involve benzyl and phenyl radicals.

引用

页码：597 / 599

页数：3

共 6 条

[1] THE [4 + 4] DIMERIZATION OF 2,3-DIMETHYLENE-2,3-DIHYDROFURAN - SECONDARY DEUTERIUM KINETIC ISOTOPE EFFECT EVIDENCE FOR A 2-STEP MECHANISM [J].