THE CONSTRUCTION OF 1,3-DIENES CONTAINING AN E-DOUBLE BOND AND AN EXO-METHYLENE GROUP

被引：12

作者：

ESHELBY, JJ

PARSONS, PJ

SILLARS, NC

CROWLEY, PJ

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

[2] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001497

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a tandem Ireland Claisen rearrangement followed by an in situ silicon mediated epoxide fragmentation provides an efficient entry into 1,3-dienes containing an E-double bond and an exo-methylene group; initial results regarding remote chirality control are reported.

引用

页码：1497 / 1498

页数：2

共 21 条

[1]

Achenbach H, 1988, Ann N Y Acad Sci, V544, P128, DOI 10.1111/j.1749-6632.1988.tb40396.x

[2] RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION [J].