ENERGY PARTITIONING IN O(1D2) REACTIONS .3. O(1D2)+NH3-]OH(NU')+NH2

被引：4

作者：

AKER, PM ^{[1
]}

OBRIEN, JJA ^{[1
]}

PARSONS, JM ^{[1
]}

SLOAN, JJ ^{[1
]}

机构：

[1] CARLETON UNIV,OTTAWA CARLETON CHEM INST,OTTAWA K1S 5B6,ONTARIO,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1986年 / 64卷 / 12期

关键词：

Reaction intermediates - Emission spectroscopy - Kinetic energy;

D O I：

10.1139/v86-380

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The vibrational distribution in the OH created by the reaction of O( D2) atoms with NH3 has been recorded directly using low pressure infrared emission spectroscopy. The relative kinetic energy of the reagents is Boltzmann at 300 K. The OH product vibrational levels are populated statistically, indicating that the reaction probably involves a long-lived ONH3 intermediate. There is some evidence that this may not be the case at higher reagent translational energies.

引用

页码：2315 / 2318

页数：4

共 26 条

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