ADSORPTION AND POLYMERIC FILM FORMATION AT MERCURY-ELECTRODES BY SOLUTIONS OF LEAD(II) AND CHELATING LIGANDS CONTAINING A THIOETHER GROUP

被引：10

作者：

PARKINSON, BA ^{[1
]}

ANSON, FC ^{[1
]}

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125

来源：

ANALYTICAL CHEMISTRY | 1978年 / 50卷 / 13期

关键词：

D O I：

10.1021/ac50035a039

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The adsorption on mercury of the complexes of several chelating carboxylate ligands bearing thioether groups with Pb(II) and some other d10 metal cations is examined. The extraordinarily large adsorption observed with a number of complexes is attributed to the formation of new phases on the mercury electrode surface. The structure of the adsorbed films may resemble the polymeric crystals formed by several metal salts of the same ligands. © 1978, American Chemical Society. All rights reserved.

引用

页码：1886 / 1891

页数：6

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