STEREOCONTROLLED CARBOTITANATION OF ALKYNYLSILANES

被引:33
作者
SNIDER, BB
KARRAS, M
机构
[1] Department of Chemistry, Princeton University, Princeton
关键词
D O I
10.1016/S0022-328X(00)91752-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Carbometalation of alkynylsilanes with 1 1 titanocene dichloride/dialkylaluminum chloride is stereospecifically cis. The alkenyltitanium intermediate can be stereospecifically protonated by aqueous sodium hydroxide or iodinated. Addition of any Lewis base to the alkenyltitanium intermediate induces decomposition of this intermediate to give an alkene by hydrogen atom abstraction from the medium, with loss of stereochemistry. © 1979.
引用
收藏
页码:C37 / C41
页数:5
相关论文
共 16 条