MOLECULAR-STRUCTURE OF ([AG13(MU-SC5H9NHME)16]13+)N, A NOVEL ONE-DIMENSIONAL NONMOLECULAR SILVER-THIOLATE

被引：16

作者：

CASALS, I

GONZALEZDUARTE, P

SOLA, J

VIVES, J

FONTBARDIA, M

SOLANS, X

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

[2] UNIV BARCELONA,DEPT CRISTALLOG & MINERAL,E-08028 BARCELONA,SPAIN

来源：

POLYHEDRON | 1990年 / 9卷 / 05期

关键词：

D O I：

10.1016/S0277-5387(00)80288-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polymeric structure of the {[Ag13(μ-SC5H9NHMe)16]13+}n cation contains Ag10S16 units linked by three silver atoms. Each unit consists of a central Ag6(μ-SR)6 core and two Ag4(μ-SR)4 rings, and comprises digonal, trigonal and tetrahedral silver and doubly- and triply-bridging sulphur atoms. © 1990.

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页码：769 / 771

页数：3

相关论文

共 6 条

[1] THE INTERTWINED DOUBLE-(-AG-SR-) INFINITY-STRAND CHAIN STRUCTURE OF CRYSTALLINE "(3-METHYLPENTANE-3-THIOLATO)SILVER, IN RELATION TO (AGSR)8 MOLECULES IN SOLUTION [J].

DANCE, IG ;

FITZPATRICK, LJ ;

RAE, AD ;

SCUDDER, ML .

INORGANIC CHEMISTRY, 1983, 22 (25) :3785-3788

[2] A MODEL FOR THE NON-MOLECULAR STRUCTURES OF THE THIOLATES, MSR, OF COPPER AND SILVER [J].

DANCE, IG .

POLYHEDRON, 1988, 7 (21) :2205-2207

[3] MONOCYCLIC COPPER AND SILVER TERTIARY ALKANETHIOLATES - FORMATION AND MOLECULAR-STRUCTURES OF (CUSBUT)4(PH3P)2, (AGSCMEET2)8(PH3P)2, AND (AGSBUT)14(PH3P)4 AND STRUCTURAL PRINCIPLES [J].

DANCE, IG ;

FITZPATRICK, LJ ;

CRAIG, DC ;

SCUDDER, ML .

INORGANIC CHEMISTRY, 1989, 28 (10) :1853-1861

[4] (AG5[MU-2-S-(CH2)3-NHME2]3[MU-2-S-(CH2)3-NME2]3)2+, THE 1ST THIOLATE COMPLEX OF A METAL WITH TRIGONAL BIPYRAMIDO-M5-TRIGONAL PRISMO-S6 POLYHEDRAL STEREOCHEMISTRY [J].

GONZALEZDUARTE, P ;

SOLA, J ;

VIVES, J ;

SOLANS, X .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) :1641-1642

[5]

GONZALEZDUARTE P, 1990, IN PRESS J CHEM SOC

[6] STERIC CONTROL OF AGGREGATION IN NEUTRAL SILVER(I) THIOLATES, [AGSR]N - CRYSTAL AND MOLECULAR-STRUCTURES OF [AGSCH(SIME3)2]8, A DISCRETE MOLECULAR BISCYCLE OF WEAKLY INTERACTING [AGSCH(SIME3)2]4 UNITS, AND OF [AGSC(SIPHME2)3]3 AND [AGSC(SIME3)3]4, DISCRETE MOLECULAR MONOCYCLES CONTAINING LINEARLY COORDINATED SILVER(I) AND DOUBLY BRIDGING MERCAPTO SULFUR DONORS FROM NOVEL STERICALLY HINDERED THIOLATE LIGANDS - A COMPARISON WITH THE NONMOLECULAR STRUCTURE OF [AG4(SCH2(SIME3))3]N(OME)N( [J].

TANG, K ;

ASLAM, M ;

BLOCK, E ;

NICHOLSON, T ;

ZUBIETA, J .

INORGANIC CHEMISTRY, 1987, 26 (10) :1488-1497