SOME REACTIONS OF THE HIGHLY POLAR ION ARH(3+)

被引：10

作者：

SMITH, D ^{[1
]}

SPANEL, P ^{[1
]}

BEDFORD, DK ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,SCH PHYS & SPACE RES,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 191卷 / 06期

关键词：

D O I：

10.1016/0009-2614(92)85593-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate coefficients for the reactions of the ion ArH3+ with CO, CH4, N2 and O2 have been measured at 80 K in a SIFT apparatus. The measured rate coefficients, k, are seen to exceed the collisional rate coefficients, k(c), as calculated using the Langevin theory for reactions involving non-polar neutral reactants. That k > k(c) is tentatively attributed to the influence of the large permanent dipole moment of the ArH3+ ion.

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页码：587 / 591

页数：5

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