CATION DIFFUSION-COEFFICIENTS IN CSCL-H2O SYSTEM OVER THE CONCENTRATION RANGE 0.009 TO 10.00 M-CENTER-DOT-DM(-3) AT 25-DEGREES-C

被引：9

作者：

CHAKRABARTI, H

机构：

[1] Solid State and Molecular Physics Division, Saha Institute of Nuclear Physics, Calcutta, 700674

来源：

APPLIED RADIATION AND ISOTOPES | 1994年 / 45卷 / 02期

关键词：

D O I：

10.1016/0969-8043(94)90007-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diffusion coeffients of the cation in CsCl-H2O system has been measured using Cs-134 tracer over the concentration range 0.009-10.00M.dm(-3) by sliding cell technique at 25 degrees C. The concentration dependence of the diffusion coefficient shows the validity of Onsager's limiting law in dilute solutions. The results were compared with the data available in the literature. The diffusion data have been used to calculate the ionic mobility and frictional coefficients to get a clear understanding of the isothermal vectorial transport process occurring in aqueous cesium chloride system.

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页码：171 / 175

页数：5

相关论文

共 12 条

[1] APPLICATION OF IRREVERSIBLE THERMODYNAMICS TO ISOTOPIC DIFFUSION .1. ISOTOPE-ISOTOPE COUPLING COEFFICIENTS FOR IONS AND WATER IN CONCENTRATED AQUEOUS-SOLUTIONS OF ALKALI-METAL CHLORIDES AT 298.16 K [J].

ANDERSON, J ;

PATERSON, R .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (06) :1335-1351

[2] ACCURATE SELF-DIFFUSION COEFFICIENTS OF LI+, NA+, AND CS+ IONS IN AQUEOUS ALKALI-METAL HALIDE SOLUTIONS FROM NMR SPIN-ECHO EXPERIMENTS [J].

BRAUN, BM ;

WEINGARTNER, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (05) :1342-1346

[3]

CHAKRABARTI H, 1993, IN PRESS J PHYS CHEM

[4]

CHAKRABARTI H, 1992, APPL RADIAT ISOTOPES, V43, P40

[5] IRREVERSIBLE THERMODYNAMIC PARAMETERS FOR ISOTHERMAL VECTORIAL TRANSPORT PROCESSES IN AQUEOUS CAESIUM CHLORIDE SOLUTIONS [J].

DUNSMORE, HS ;

JALOTA, SK ;

PATERSON, R .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (07) :1061-&

[6] TRANSPORT PHENOMENA ON CONCENTRATED SOLUTIONS OF ALKALINE AND ALKALINE-EARTH HALOGENIDES [J].

FORTES, JM ;

MERCIER, M ;

MOLENAT, J .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1974, 71 (02) :164-170

[7] EFFECT OF STRUCTURE ON ION SELF-DIFFUSION IN CONCENTRATED ELECTROLYTE SOLUTIONS [J].

HERTZ, HG ;

HOLZ, M ;

MILLS, R .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1974, 71 (10) :1355-1362

[8] EFFECT OF STRUCTURE ON SELF-DIFFUSION IN CONCENTRATED ELECTROLYTES - RELATIONSHIP BETWEEN WATER AND IONIC SELF-DIFFUSION COEFFICIENTS [J].

HERTZ, HG ;

MILLS, R .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1976, 73 (05) :499-508

[9] The transference number of barium chloride as a function of the concentration [J].

Jones, G ;

Dole, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1929, 51 (1-4) :1073-1091

[10]

LIUKKONEN S, 1973, ACTA POLYTECH SCAND, V113, P36