AGGREGATION OF ORGANOMETALLIC COMPLEX PILLARS IN SYNTHETIC FLUORHECTORITE AND MONTMORILLONITE

被引：17

作者：

TSVETKOV, F ^{[1
]}

WHITE, J ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,GPO BOX 4,CANBERRA,ACT 2601,AUSTRALIA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1988年 / 110卷 / 10期

关键词：

CATALYSTS; -; Materials; ORGANOMETALLICS;

D O I：

10.1021/ja00218a029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the first measurement of the inplane packing of pillars in smectites as a function of relative pillar charge (pillar ion charge/clay surface charge ratio). Sodium montmorillonite and a high-charge synthetic fluorhectorite were pillared with complex ions: Ir(diamsar)**3** plus , Hg(diamsarH//2)**4** plus , and Hg(diamsar)**2** plus resulting in well-oriented samples. Six orders of the c-axis X-ray diffraction were resolved as well as peaks corresponding to the lateral free distance between cations (in transmission mode). The peaks in plane have Warren line shapes, on analysis of which give the true interpillar distances.

引用

页码：3183 / 3187

页数：5

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