NMR DEMONSTRATION OF REARRANGEMENT OF 15N-LABELLED P-ANISOLEDIAZONIUM ION

被引：20

作者：

LEWIS, ES

KOTCHER, PG

机构：

[1] Department of Chemistry, Rice University, Houston

来源：

TETRAHEDRON | 1969年 / 25卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)83027-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The conversion of p-CH3OC6H4N2+ to the hydrazine and then to the benzaldehyde hydrazone gave a stable substance in which the proton NMR could be used to locate a 15N label. In contrast to an earlier study on benzenediazonium ion by a similar method, this analysis showed that the α-15N label in the diazonium salt migrates during hydrolysis to the β position to about the extent indicated by a degradative method. © 1969.

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页码：4873 / &

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