NONCONVENTIONAL SYNTHESES OF BETA-ALUMINA POWDERS

被引:15
作者
COLUCCI, G
NEGRO, A
VISCONTE, E
PIJOLAT, C
LALAUZE, R
机构
[1] Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, 1029 Torino
[2] Departement de Chimie-Physique des Processus Industriels, Ecole Nationale Supérieure des Mines de Saint-Etienne, 42023 Saint-Etienne Cédex 02, 158, Cours Fauriel
关键词
D O I
10.1016/0272-8842(90)90070-V
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Because of its high ionic conductivity β-alumina is currently used as a solid electrolyte for gas sensors. In order to control the morphological properties and sodium contents of powder used in such applications, it has been produced by two types of synthesis: by thermal denitrification and by the use of a gel. The various β-alumina crystallization mechanisms have been characterized. They illustrate the role played by certain precursors which, when present, are capable of affecting the ratio of β and β″ phases. Electrical conductivity measurements by AC technique at 300-500°C were carried out. Ageing tests confirmed the much higher stability of the gel-prepared products. © 1990.
引用
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页码:225 / 229
页数:5
相关论文
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[2]  
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[3]  
Elliott, Huggins, Phases in the System NaAlO2-Al2O3, Journal of the American Ceramic Society, 58, (1975)