UNUSUAL CHEMOSELECTIVITY AND STEREOSELECTIVITY IN THE ADDITION OF CHIRAL AMINOALCOHOLS TO ACHIRAL NITROALKENES

被引：38

作者：

MORRIS, ML ^{[1
]}

STURGESS, MA ^{[1
]}

机构：

[1] UNIV ARKANSAS,DEPT CHEM & BIOCHEM,FAYETTEVILLE,AR 72701

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 01期

基金：

美国国家科学基金会;

关键词：

CHIRAL AMINES; ACHIRAL NITROALKENES; FACIAL SELECTIVITY; H-BONDING;

D O I：

10.1016/S0040-4039(00)60053-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral aminoalcohols react with achiral nitroalkenes in a highly chemoselective manner depending on the aminoalcohol. Under optimum conditions, the addition reaction is almost stereospecific.

引用

页码：43 / 46

页数：4

共 11 条

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