SYNTHESIS OF 2-DEOXYXYLOLACTONE FROM GLYCEROL DERIVATIVES VIA HIGHLY ENANTIOSELECTIVE CARBON-HYDROGEN INSERTION REACTIONS

被引：37

作者：

DOYLE, MP

DYATKIN, AB

TEDROW, JS

机构：

[1] Department of Chemistry, Trinity University, San Antonio

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(00)76684-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diazodecomposition of 1,3-dialkoxy-2-propyl diazoacetates catalyzed by chiral dirhodium(ii) carboxamides results in highly enantioselective and diastereoselective carbon-hydrogen insertion which forms 3,5-dialkyl 2-deoxyxylolactones in up to 98% enantiomeric excess.

引用

页码：3853 / 3856

页数：4

共 20 条

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[7] ELECTRONIC AND STERIC CONTROL IN CARBON HYDROGEN INSERTION REACTIONS OF DIAZOACETOACETATES CATALYZED BY DIRHODIUM(II) CARBOXYLATES AND CARBOXAMIDES
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