SYNTHESIS, CHARACTERIZATION AND STRUCTURAL ASPECTS OF DIORGANOTELLURIUM(IV) COMPOUNDS CONTAINING (TE-S) BONDS

被引：17

作者：

SRIVASTAVA, TN

SINGH, JD

SRIVASTAVA, SK

机构：

[1] JIWAJI UNIV,SCH STUDIES CHEM,GWALIOR 474011,INDIA

[2] UNIV LUCKNOW,DEPT CHEM,LUCKNOW 226007,UTTAR PRADESH,INDIA

来源：

POLYHEDRON | 1990年 / 9卷 / 07期

关键词：

D O I：

10.1016/S0277-5387(00)84295-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diorganotellurium(IV) compounds containing (TeS) bonds of the general formulae [R2Te(S2POGO)2] [R = Ph or p-MeOC6H4; G = CH(Me)CH(Me),Me2CCMe2,CH2C(Me2)CH2, (Me)CHCH2C(Me2), CH2C(Et2)CH2] have been prepared by the reaction of R2Te(OR′)2 (R′ = Me or Et) and corresponding O,O′-alkylene dithiophosphoric acids or by the reaction of R2TeCl2 with [NH4S2POGO] in anhydrous toluene. The products have been characterized using analytical and spectroscopic (IR, 1H, 13C, 31P and 125Te NMR) data. The products are monomeric in nature and their possible structures are discussed. © 1990.

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页码：943 / 948

页数：6

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