AN ASYMMETRIC DIELS-ALDER CYCLOADDITION TO ALPHA-HYDROXY-ALPHA-PHENYL-ORTHO-QUINODIMETHANE

被引：17

作者：

CHARLTON, JL

MADDAFORD, S

KOH, K

BOULET, S

SAUNDERS, MH

机构：

[1] Department of Chemistry, University of Manitoba, Winnipeg

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 04期

关键词：

D O I：

10.1016/S0957-4166(00)80169-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cycloaddition of the fumarate of methyl (R)-mandelate to alpha-hydroxy-alpha-phenyl-o-quinodimethane 3 gives a single diastereomer in high yield. The absolute stereochemistry of the cycloadduct is established and the potential of the reaction for asymmetric lignan synthesis is discussed.

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页码：645 / 648

页数：4

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