DICHLOROBIS(5,7-DIMETHYL[1,2,4]TRIAZOLO-[1,5-A]PYRIMIDINE-N(3))ZINC(II)

被引：24

作者：

SALAS, JM ^{[1
]}

ROMERO, MA ^{[1
]}

RAHMANI, A ^{[1
]}

FAURE, R ^{[1
]}

机构：

[1] UNIV LYON 1,CHIM ANALYT LAB 2,F-69622 VILLEURBANNE,FRANCE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193009448

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and crystal structure of the title compound, [ZnCl2(C7H8N4)2], obtained by the reaction of zinc(II) chloride with 5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine (dmtp), are reported. The Zn atom is tetrahedrally coordinated by two Cl atoms at distances of 2.197 (1) and 2.2499(8) angstrom and to two N3 atoms of two independent molecules of dmtp at distances of 2.058 (2) and 2.020 (2) angstrom. One of the dmtp ligand types is associated in couples by stacking interactions with an interplanar distance of 3.36 (1) angstrom.

引用

页码：510 / 512

页数：3

共 20 条

[1] CRYSTAL STRUCTURE OF DICHLOROBIS(1-METHYLTETRAZOLE)ZINC(II) [J].

BAENZIGER, NC ;

SCHULTZ, RJ .

INORGANIC CHEMISTRY, 1971, 10 (04) :661-+

[2] CRYSTAL-STRUCTURE OF DICHLORO BIS(1-METHYLCYTOSINE)ZINC(II) [J].

BEAUCHAMP, AL .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1984, 91 (01) :33-38

[3] STRUCTURE OF 1-PERCENT COPPER(II)-DOPED DICHLOROBIS(1,2-DIMETHYLIMIDAZOLE)ZINC(II) [J].

BHARADWAJ, PK ;

SCHUGAR, HJ ;

POTENZA, JA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :754-757

[4]

BIAGINICINGI M, 1983, INORG CHIM ACTA, V72, P81

[5]

BIAGINICINGI M, 1986, ACTA CRYSTALLOGR C, V42, P427

[6]

BIAGINICINGI M, 1985, INORG CHIM ACTA, V101, P49

[7]

BIAGINICINGI M, 1984, INORG CHIM ACTA, V86, P137

[8] RELATION BETWEEN STRUCTURES AND SPECTROSCOPIC PROPERTIES OF GROUP-2B METAL [M(CHELATE)X2] COMPLEXES (X=CL,BR,I) - CRYSTAL AND MOLECULAR-STRUCTURE OF [H2NCH2(CH3)2CCH2NH2]MX2 COMPLEXES (M=ZN,X=CL, BR,M=CD, X=BR) [J].

CARIATI, F ;

CIANI, G ;

MENABUE, L ;

PELLACANI, GC ;

RASSU, G ;

SIRONI, A .

INORGANIC CHEMISTRY, 1983, 22 (13) :1897-1902

[9] TRANSITION-METAL THIOCYANATES OF 5,7-DIMETHYL[1,2,4] TRIAZOLO [1,5-A]-PYRIMIDINE STUDIED BY SPECTROSCOPIC METHODS - THE CRYSTAL-STRUCTURES OF DIAQUABIS (DIMETHYLTRIAZOLOPYRIMIDINE-N-3) BIS (THIOCYANATO-N) CADMIUM(II) AND BIS (DIMETHYLTRIAZOLOPYRIMIDINE-N-3) BIS (THIOCYANATO-S)-MERCURY(II) [J].

DILLEN, J ;

LENSTRA, ATH ;

HAASNOOT, JG ;

REEDIJK, J .

POLYHEDRON, 1983, 2 (03) :195-201

[10] CHARACTERIZATION OF COPPER(II) COORDINATION-COMPOUNDS OF 5,7-DIMETHYL[1,2,4]TRIAZOLO[1,5-A]PYRIMIDINE - THE CRYSTAL-STRUCTURE OF DIAQUATETRAKIS(5,7-DIMETHYL[1,2,4]TRIAZOLO[1,5-A]PYRIMIDINE-N3)-COPPER(II) HEXAFLUOROPHOSPHATE [J].

FAVRE, TLF ;

HAASNOOT, JG ;

REEDIJK, J .

POLYHEDRON, 1986, 5 (09) :1405-1411

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