Effect of physico-chemical degradation of epoxy resin on partial discharge behavior

Epoxy resin coated electrode specimens were subjected to partial discharges (PD) in air at twice the discharge inception voltage for durations ranging to 5000 h. The PD behavior was characterized by a transition from initially large pulse type discharges (similar to 200 to 300 pC) to either small pulse (similar to 1 pC), pseudoglow, glow discharge, or a combination thereof. Although these different forms of discharges were capable of occurring simultaneously, each type tended to prevail over certain periods of the exposure time. The physical and chemical nature of the degradation products formed on the surfaces of the epoxy resin also varied accordingly, indicating that each discrete form of discharge exerts its particular effect on the overall degradation process. Droplet formation on the central portion of the epoxy surfaces typified the large pulse discharge regime, whilst crystals formed within the transition region over which small discharge pulses (similar to 1 pC) were usually superimposed upon a continuous glow (pseudoglow and true glow regime). The droplets were identified as being partially comprised of a mixture of acids, mainly formic, glycolic, glyoxalic and nitric acids, whilst the crystals consisted of hydrated oxalic acid. Since similar results were obtained with discharges in both air and nitrogen, the effects of gas phase reactions on the PD activity would appear to be only of secondary importance compared to the reactions taking place on the surface of the epoxy resin. Since the test cell design did not allow any pressure variation within the discharge gap, the observed discharge transition cannot be attributed to pressure changes such as may take place within occluded cavities. Nevertheless, the transition observed here is similar to what is found with actual stator bar type insulation, suggesting that pronounced chemical and physical modifications on the surface of the physical cavity inclusions in the bar insulation may account for the characteristic PD behavior observed as a function of time.