INTERCONVERSIONS IN CYCLOSILAZANES AND THEIR APPLICATION TO SIN-CERAMICS

被引：21

作者：

DIPPEL, K

WERNER, E

KLINGEBIEL, U

机构：

[1] Institute of Inorganic Chemistry, Goettingen University, D-3400, Goettingen

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 64-5卷 / 1-4期

关键词：

D O I：

10.1080/10426509208041123

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rearrangements occur very frequently in reactions of cyclosilazanes. Wehave found an equilibrium between the eight-, six-, and four–membered ringanions, which is strongly dependent on thermal and kinetic effects, the choice of substituents and the properties of the attacking group. Knowledge of the interconversion mechanisms has enabled us to reparesilyl-bridged and coupled cyclosilazanes of high molecular weight. Thesecoumpounds are useful precursors of SiN-ceramics. © 1992, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：15 / 24

页数：10

共 8 条

[1] ALKYLSILAZANES AND SOME RELATED COMPOUNDS [J].