REDOX CHEMISTRY OF SUBSTITUTED BENZENES - THE ONE-ELECTRON REDUCTION POTENTIALS OF METHOXY-SUBSTITUTED BENZENE RADICAL CATIONS

被引：93

作者：

JONSSON, M ^{[1
]}

LIND, J ^{[1
]}

REITBERGER, T ^{[1
]}

ERIKSEN, TE ^{[1
]}

MERENYI, G ^{[1
]}

机构：

[1] ROYAL INST TECHNOL,DEPT PHYS CHEM,S-10044 STOCKHOLM 70,SWEDEN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 43期

关键词：

D O I：

10.1021/j100145a027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The one-electron reduction potentials of seven methoxy-substituted benzene radical cations in aqueous solutions have been determined by means of pulse radiolysis. In addition, the rate of the reaction between OH- and the radical cation has been measured for 1,4- and 1,2-dimethoxybenzene. A general equation for reduction potentials of 1,4-substituted benzene radical cations has been derived taking into account experimental results from this work and results and estimations found in the literature.

引用

页码：11278 / 11282

页数：5

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