THEORETICAL-STUDY OF THE REDOX AND ACID-BASE EQUILIBRIA OF 2,6-DICHLOROINDOPHENOL IMMOBILIZED ON AMBERLITE XAD-4

被引：3

作者：

GOODLET, G ^{[1
]}

NARAYANASWAMY, R ^{[1
]}

PRZYBYLKO, A ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT INSTRUMENTAT & ANALYT SCI,MANCHESTER M60 1QD,ENGLAND

来源：

ANALYTICA CHIMICA ACTA | 1994年 / 287卷 / 03期

关键词：

IMMOBILIZED REAGENT; MATHEMATICAL MODELING; REDOX INDICATOR;

D O I：

10.1016/0003-2670(93)E0602-E

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

By using three equations, viz., the Nernst equation, the acid-base dissociation constant equation and the equation for the Kubelka-Munk function for reflectance, an equation describing the redox behaviour of the immobilised indicator 2,6-dichloroindophenol has been formulated. After determination of the acid dissociation constant of the reduced form of the indicator, theoretical responses were calculated and compared to the experimental responses. The results indicate that the redox equilibrium involves a one-electron transfer in the pH range 2 to 5.

引用

页码：285 / 291

页数：7

共 8 条

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[4]

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[7]

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[8]

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