ELECTROCHEMICAL SOLAR-CELLS BASED ON LAYER-TYPE TRANSITION-METAL COMPOUNDS - PERFORMANCE OF ELECTRODE MATERIAL

被引：132

作者：

TRIBUTSCH, H

机构：

[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft, D-1000 Berlin 33

来源：

SOLAR ENERGY MATERIALS | 1979年 / 1卷 / 3-4期

关键词：

D O I：

10.1016/0165-1633(79)90044-3

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The effect of doping of MoSe2 (band gap 1.4 eV) as well as the influence of the electrochemical potential of the redox-couple in the electrolyte have been investigated in an effort to optimize solar cells based on layer compounds. It is shown that in the case of I-/I2 the mechanism of photopotential generation is assisted by a favourable chemical modification of the electrode surface which introduces both negative charges into the double layer and traps for holes into the space charge layer. The effect is traced to the formation and reaction behaviour of a five-valent Mo(V)-I complex. The MoSe2:I-/I2-cell could be improved to an energy conversion efficiency of 8% for monochromatic and 4% for solar radiation. Its good stability was established by continued operation at 10 mA/cm2 for 10 months. This system cannot compete with solid state solar cells, but it could possibly be developed as hybride cell for the simultaneous production of heat and electricity. © 1979.

引用

页码：257 / 269

页数：13

共 15 条

[1]

Tributsch, Bennett, J. Electroanal. Chem., 81, (1977)

[2]

Tributsch, Z. Naturforschung, 32 A, (1977)

[3]

Tributsch, Ber. Bunsenges. Phys. Chem., 81, (1977)

[4]

Tributsch, Ber. Bunsenges. Phys. Chem., 82, (1978)

[5]

Tributsch, J. Electrochem. Soc., 125, (1978)

[6]

Gobrecht, Gerischer, Tributsch, Electrochemical Solar Cell Based on the d-Band Semiconductor Tungsten-Diselenide, Berichte der Bunsengesellschaft für physikalische Chemie, 82, (1978)

[7]

Levy, Schmid, Berger, Electrical properties of layered MoSe2single crystals doped with Nb and Re, Philosophical Magazine, 34, (1976)

[8]

Gobrecht, Tributsch, Gerischer, Performance of Synthetical n-MoSe[sub 2] in Electrochemical Solar Cells, Journal of The Electrochemical Society, 125, (1978)

[9]

Razumney, Wroblowa, Energy Conversion, 13, (1973)

[10]

Gerischer, J. Electroanal. Chem., 58, (1975)

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