SESQUITERPENE LACTONES OF EUPATORIUM-SEROTINUM

被引:39
作者
HERZ, W [1 ]
GROOTE, RD [1 ]
MURARI, R [1 ]
KUMAR, N [1 ]
BLOUNT, JF [1 ]
机构
[1] HOFFMANN LA ROCHE INC,DIV RES,NUTLEY,NJ 07110
关键词
D O I
10.1021/jo01329a039
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The isolation of four new germacranolides from Eupatorium serotinum Michx. is reported. Structures and stereochemistry of 1a, b and 2a were established by NMR spectrometry and chemical interconversions. The structure of euserotin (3), an unusual germacradienecarboxylic acid, was elucidated by X-ray crystallography. The flavones pectolinarigenin and hispidulin were also found. © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码:2784 / 2788
页数:5
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