PHOTODEPLETION SPECTROSCOPY ON CHARGE RESONANCE BAND OF (C6H6)2+ AND (C6H6)3+

被引：56

作者：

OHASHI, K ^{[1
]}

NISHI, N ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC SCI,DEPT CHEM,FUKUOKA 812,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 07期

关键词：

D O I：

10.1021/j100186a030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photodepletion spectra of (C6H6)2+ and (C6H6)3+ are obtained from the depletion yields of the parent ions as functions of photodissociation wavelengths of 750-970 nm. The spectrum of (C6H6)2+ shows a broad and featureless band with a maximum at almost-equal-to 920 nm and an (estimated) width of almost-equal-to 2000 cm-1. The spectrum of (C6H6)3+ shows a similar absorption to the (C6H6)2+ band, suggesting that the (C6H6)3+ band is due to the charge resonance transition in the dimer ion subunit.

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页码：2931 / 2932

页数：2

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