FLUORINE-19 NUCLEAR MAGNETIC RESONANCE INVESTIGATIONS OF COMPLEXES OF ANTIMONY PENTAFLUORIDE .2. REACTIONS OF ANTIMONY PENTAFLUORIDE WITH WATER, SULFURIC ACID, AND FLUOROSULFURIC ACID

被引：29

作者：

DEAN, PAW

GILLESPI.RJ

机构：

[1] Department of Chemistry, McMaster University, Hamilton, Ontario

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 26期

关键词：

D O I：

10.1021/ja01054a011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that water reacts with antimony pentafluoride in solution in SO2 to form the complexes SbF5·OH2 and SbF5·OH2·SbF5. These complexes undergo ligand redistribution reactions such as 2SbF5·OH2 ⇆ SbF4(OH2)2+ + SbF6−. Excess SbF5 forms Sb2F11− and SbF5·SO2. With sulfuric acid, the complexes SbF5·OSO-(OH)2 and F6Sb·OS(OH)2O·SbF5 are formed. Ligand redistribution reactions similar to those proposed for the SbF5-H2O system also occur in the SbF5-H2SO4 and SbF5-FSO3H systems. © 1969, American Chemical Society. All rights reserved.

引用

页码：7264 / &

共 8 条

[1]

COMMEYRAS A, 1969, J AM CHEM SOC, V91, P2929

[2] ANTIMONY TETRAFLUORIDE MONOFLUOROSULPHATE - PREPARATION PROPERTIES + STRUCTURE [J].