ALKYL-PLATINUM(II) AND ARYL-PLATINUM(II) COMPLEXES FROM K2[PTCL4] AND TETRAORGANOTIN COMPOUNDS IN DIMETHYLSULFOXIDE - PREPARATION AND REACTIONS OF COMPLEXES [PTR2(DMSO)2] AND [PTR(C] (DMSO)2]

被引：18

作者：

EABORN, C

KUNDU, K

PIDCOCK, A

机构：

[1] School of Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 170卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)83201-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between K2[PtCl4] and a variety of tetraorganotin compounds SnMe3R (R = Me, aryl) in DMSO gives the complexes cis-[PtR2(DMSO)2] and trans-[PtR(Cl)(DMSO)2] in which the DMSO ligands are bound to Pt through S in the solid state. The DMSO ligands are easily displaced by a variety of N, P, As and Sb donors. © 1979.

引用

页码：C18 / C20

页数：3

共 2 条

[1] PREPARATION OF ARYLPLATINUM(II) COMPLEXES - INTERACTION OF DICHLORO-( ETA-CYCLO-OCTA-1,5-DIENE)PLATINUM(II) AND ARYLTRIMETHYLSTANNANES [J].

EABORN, C ;

ODELL, KJ ;

PIDCOCK, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (04) :357-368

[2] PALLADIUM(II) AND PLATINUM(II) ALKYL SULFOXIDE COMPLEXES - EXAMPLES OF SULFUR-BONDED, MIXED SULFUR-BONDED AND OXYGEN-BONDED, AND TOTALLY OXYGEN-BONDED COMPLEXES [J].

PRICE, JH ;

SCHRAMM, RF ;

WAYLAND, BB ;

WILLIAMSON, AN .

INORGANIC CHEMISTRY, 1972, 11 (06) :1280-+

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