学术探索
学术期刊
新闻热点
数据分析
智能评审

STRUCTURE OF A COMPLEX OF 1,4,8,11-TETRAAZACYCLOTETRADECANE (CYCLAM) WITH ZINC(II) CHLORIDE

被引：18
作者：
ALCOCK, NW
BERRY, A
MOORE, P
机构：
[1] Department of Chemistry, University of Warwick
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270191008454
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bis[mu-chloro-(1,4,8,11-tetraazacyclotetradecane)zinc(II)] tetrachlorozincate(II) hemihydrate, [ZnCl(C10H24N4)]2n.n[ZnCl4]2-.(n/2)H2O, M(r) = 818.5 for n = 1, tetragonal, 142dBAR, a = 17.950 (5), c = 10.907 (2) angstrom, V = 3514 (1) angstrom 3, Z = 4, D(m) = 1.52, D(x) = 1.55 g cm3, lambda(Mo K-alpha) - 0.71069 angstrom, mu = 25.7 cm-1, T = 290 K, R = 0.095 for 750 unique observed [I/sigma(I) greater-than-or-equal-to 2.0] reflections. The structure consists of infinite -Cl-[Zn(cyclam)]2+ -Cl- chains interspersed with [ZnCl4]2- ions. The mean Zn-N and Zn-Cl (chain) distances are 2.13 (1) and 2.730 (4) angstrom, while the Zn-Cl bond length in the anion is 2.288 (5) angstrom.
引用
收藏
页码：16 / 19
页数：4
相关论文
共 9 条
[1]   COMPARISON OF STRUCTURE AND DYNAMIC PROPERTIES OF ANIONO(1,4,8,11-TETRAMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE)ZINC(II) PERCHLORATE COMPLEXES IN NITROMETHANE SOLUTIONS, AND CRYSTAL AND MOLECULAR-STRUCTURE OF CHLORO-COMPLEX [J].
ALCOCK, NW ;
HERRON, N ;
MOORE, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (10) :1282-1288
[2]   HEAVY-METAL MACROCYCLIC COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF COMPLEXES OF 1,5,9,13-TETRA-AZACYCLOHEXADECANE WITH CD(NO3)2, HGCL2, PBCL2, AND PB(NO3)2 [J].
ALCOCK, NW ;
CURZON, EH ;
MOORE, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (12) :2813-2820
[3]  
Barefield E.K., 1976, INORG SYNTH, V16, P220
[4]   COMPLEXES OF NICKEL(2) WITH A CYCLIC TETRADENTATE SECONDARY AMINE [J].
BOSNICH, B ;
TOBE, ML ;
WEBB, GA .
INORGANIC CHEMISTRY, 1965, 4 (08) :1109-&
[5]  
BOSNICH B, 1965, J CHEM SOC CHEM COMM, P97
[6]   STRUCTURE OF [ZNCL(C4H8O)(MU-CL)]INFINITY [J].
BOTTOMLEY, F ;
FERRIS, EC ;
WHITE, PS .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :816-817
[7]   UNEXPECTED AND FACILE EQUILIBRATION OF 6-CO-ORDINATE BIS(SOLVENTO)-(R,S,S,R)(1,4,8,11-TETRAMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE)NICKEL-(II) IONS WITH THE 5-CO-ORDINATE MONO(SOLVENTO)-(R,S,R,S)-COMPLEXES IN SOME COORDINATING SOLVENTS [J].
MOORE, P ;
SACHINIDIS, J ;
WILLEY, GR .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (09) :522-523
[8]  
SHELDRICK GM, 1986, SHELXTL USER MANUAL
[9]   STRUCTURE OF ZN(CYCLAM)(CLO4)2 [J].
TYSON, TA ;
HODGSON, KO ;
HEDMAN, B ;
CLARK, GR .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1638-1640
1