REACTION WITH AMINES OF THE ADDUCT FORMED BETWEEN (CINNAMALDEHYDE)TETRACARBONYLIRON PI-COMPLEX AND BF3 - MOLECULAR-STRUCTURE OF THE FORMED SIGMA-TETRACARBONYLIRON COMPLEXES OF CINNAMALDEHYDE IMINES

被引：26

作者：

NESMEYANOV, AN ^{[1
]}

RYBIN, LV ^{[1
]}

STELZER, NA ^{[1
]}

STRUCHKOV, YT ^{[1
]}

BATSANOV, AS ^{[1
]}

RYBINSKAYA, MI ^{[1
]}

机构：

[1] ACAD SCI USSR,INST ORGANOELEMENT CPDS,MOSCOW V-71,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)84823-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The adduct formed on reaction of boron trifluoride etherate with (π-PhCHCHCHO)Fe(CO)4 by addition of BF3 to the oxygen atom of the aldehyde group, reacts with primary amines to give σ-N-tetracarbonyliron derivatives of cinnamaldehyde imines via (enimonium)tetracarbonyliron π-complexes. The structure of the former complexes is established by X-ray analysis and the effect of steric factors on π → σ(N) rearrangernent is discussed. © 1979.

引用

页码：399 / 408

页数：10

共 10 条

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