STEREOSELECTIVE SYNTHESIS OF 7-THIA-16-OXA-14BETA-ESTRONES

被引：6

作者：

KANO, S ^{[1
]}

TANAKA, K ^{[1
]}

HIBINO, S ^{[1
]}

SHIBUYA, S ^{[1
]}

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 09期

关键词：

D O I：

10.1021/jo01323a053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and stereoselective synthesis of 3-methoxy-7-thia-16-oxa-14β-1, 3, 5(10), 9(11)-estratetraen-17-one was achieved by an application of the Diels-Alder reaction between 7-methoxy-4-vinylthiaisochromene with citraconic anhydride, followed by reduction of the Diels-Alder adduct with NaBH4. © 1979, American Chemical Society. All rights reserved.

引用

页码：1580 / 1582

页数：3

共 14 条

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