PALLADIUM(II) AND PLATINUM(II) COMPLEXES WITH CHELATING SULFINYL FUNCTIONS

被引：16

作者：

CHOOI, SYM ^{[1
]}

LEUNG, PH ^{[1
]}

MOK, KF ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE, DEPT CHEM,KENT RIDGE, SINGAPORE 0511, SINGAPORE

来源：

INORGANICA CHIMICA ACTA | 1993年 / 205卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)85545-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of palladium and platinum complexes of (+/-)-Ph2ECH2CH2S(O)Me (E = P, As) is described. A single crystal X-ray diffraction study of [(+/-)-Ph2PCH2CH2S(O)MePdCl2] reveals a square-planar geometry at the central atom which is attached by a chelate ring via the P-S donors of the sulfinyl-substituted ligand. Similar structures are assigned to all four complexes by H-1 NMR spectroscopy in d3-acetonitrile solutions. Oxygen-metal bonds are not involved in these molecules.

引用

页码：245 / 247

页数：3

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