SYNTHESIS OF NEW STEREOCHEMICALLY NONRIGID MOLYBDENUM-ALLYL COMPLEXES CONTAINING THE BIS(3,5-DIMETHYLPYRAZOLYL)METHANE LIGAND

被引：16

作者：

JOSHI, VS

SARKAR, A

RAJAMOHANAN, PR

机构：

[1] NATL CHEM LAB,DIV ORGAN CHEM 1,POONA 411008,MAHARASHTRA,INDIA

[2] NATL CHEM LAB,DIV PHYS CHEM,POONA 411008,MAHARASHTRA,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 409卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)80020-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient preparation of LMo(CO)4 (L = bis(3,5-dimethylpyrazolyl)methane) and the syntheses of several fluxional cis-LMo(CO)2(allyl) compounds are reported. Their proton NMR spectra are discussed.

引用

页码：341 / 346

页数：6

共 29 条

[1] AQUEOUS ALLYLMOLYBDENUM(II) CHEMISTRY [J].

BRISDON, BJ ;

CARTWRIGHT, M ;

HODSON, AG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 277 (01) :85-90

[2] CYCLOMETALLATION OF POLYDENTATE LIGANDS CONTAINING PYRAZOLE GROUPS, INCLUDING THE SYNTHESIS OF PLATINUM(IV) COMPLEXES WITH TRIPODAL [N-C-N]- LIGAND SYSTEMS [J].

CANTY, AJ ;

HONEYMAN, RT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 387 (02) :247-263

[3] STRONG INTERACTION BETWEEN AN ALIPHATIC CARBON HYDROGEN-BOND AND A METAL ATOM - THE STRUCTURE OF (DIETHYLBIS(1-PYRAZOLYL)BORATO)ALLYLDICARBONYLMOLYBDENUM(II) [J].

COTTON, FA ;

LUCK, RL .

INORGANIC CHEMISTRY, 1989, 28 (16) :3210-3213

[4] ASPECTS OF CHIRALITY RETENTION IN REARRANGEMENTS OF PSEUDO-OCTAHEDRAL MOLYBDENUM AND TUNGSTEN COMPLEXES [J].

FALLER, JW ;

HAITKO, DA ;

ADAMS, RD ;

CHODOSH, DF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (04) :865-876

[5] ACTIVATION OF A VINYL CARBON HYDROGEN-BOND IN A TRIS(PYRAZOLYL)BORATOIRIDIUM COMPLEX - THE X-RAY CRYSTAL-STRUCTURE OF [IRH(HB(PZ)3)(OMICRON-C8H13)(ETA-2-C8H14)] [J].

FERNANDEZ, MJ ;

RODRIGUEZ, MJ ;

ORO, LA ;

LAHOZ, FJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (10) :2073-2076

[6] THE 1ST POLYHYDRIDES STABILIZED ONLY BY N-DONOR LIGANDS, [(HB(PZ)3)REH6] AND [(CH2(PZ)2)REH7] [J].

HAMILTON, DG ;

LUO, XL ;

CRABTREE, RH .

INORGANIC CHEMISTRY, 1989, 28 (16) :3198-3203

[7] (TRIS(PYRAZOLYL)HYDROBORATO)MAGNESIUM AND (TRIS(PYRAZOLYL)HYDROBORATO-ALUMINUM ALKYL DERIVATIVES - ALKYL EXCHANGE WITH METHYL-IODIDE AND ENOLATE FORMATION WITH ACETONE [J].

HAN, R ;

LOONEY, A ;

PARKIN, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7276-7278

[8] ALLYLIC CHLORIDES .9. PREPARATION OF CIS AND TRANS CROTYL CHLORIDE [J].

HATCH, LF ;

NESBITT, SS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (02) :727-730

[9] A RAPID MILD PROCEDURE FOR PREPARATION OF ALKYL CHLORIDES AND BROMIDES [J].

HOOZ, J ;

GILANI, SSH .

CANADIAN JOURNAL OF CHEMISTRY, 1968, 46 (01) :86-&

[10] SUBSTITUTED METAL-CARBONYLS .2. FACILE SYNTHESES OF MIXED-LIGAND TRICARBONYL COMPLEXES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN [J].

HOR, TSA .

INORGANICA CHIMICA ACTA, 1987, 128 (01) :L3-L4

← 1 2 3 →