MOTION OF AROMATIC-MOLECULES IN BILE-ACID MICELLES

被引:13
作者
FUNG, BM
THOMAS, L
机构
[1] University of Oklahoma, Department of Chemistry, Norman
基金
美国国家卫生研究院;
关键词
D O I
10.1016/0009-3084(79)90064-1
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Deuterium spin-lattice relaxation time (T1) of perdeuterobenzene and perdeuteronaphthalene dissolved in aqueous solutions of sodium deoxycholate and sodium cholate was studied. By comparing the experimental data and theoretical calculations, it was concluded that benzene and naphthalene are not held stationary in the bile acid micelles, and their molecular planes have certain librational motion. In addition, benzene undergoes rapid rotation about the C6 axis, but naphthalene does not rotate in its molecular plane. © 1979.
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页码:141 / 148
页数:8
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