LIQUID-PHASE FLUORINATION OF 1,1,1-TRICHLOROETHANE

被引：8

作者：

BRUNET, S ^{[1
]}

BATIOT, C ^{[1
]}

BARRAULT, J ^{[1
]}

BLANCHARD, M ^{[1
]}

机构：

[1] ECOLE SUPER INGN POITIERS,CATALYSE LAB,CNRS,URA 350,40 AVE RECTEUR PINEAU,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 59卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80201-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of HF with SbCl5 at 60-degrees-C and 1 MPa provides antimony mixed halides whose empirical formulae have been determined. The product is a mixture of SbClF4 and SbClF2 solvated by HF and its activity has been measured for the conversion of 1,1,1-trichloroethane (F140a) into mono- and difluorochloroethane (F141b and F142b).

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页码：33 / 39

页数：7

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