STUDIES OF BICUVOX.10 BY CONDUCTIVITY MEASUREMENTS AND DIFFERENTIAL THERMAL-ANALYSIS

被引：27

作者：

REISELHUBER, K

DORNER, G

BREITER, MW

机构：

[1] Institut für Technische Elektrochemie, TU Wien, A-1060 Wien

来源：

ELECTROCHIMICA ACTA | 1993年 / 38卷 / 07期

关键词：

OXYGEN ION CONDUCTOR; CONDUCTIVITY; PHASE CHANGES; TERNARY OXIDE;

D O I：

10.1016/0013-4686(93)87016-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Powders of BICUVOX.10 with different grain size distribution were prepared and characterized by measurements of their X-ray diffraction spectra, TGA and DTA curves. The density of sintered pellets was determined and the specific conductivity was obtained as a function of temperature by a four-probe technique. A different conductivity behavior of pellets with large grains and with small grains is observed during the heating cycle. It is related to a reordering process occurring between 450 and 500-degrees-C.

引用

页码：969 / 973

页数：5

共 8 条

[1] THE BIMEVOX SERIES - A NEW FAMILY OF HIGH PERFORMANCES OXIDE ION CONDUCTORS
ABRAHAM, F
BOIVIN, JC
MAIRESSE, G
NOWOGROCKI, G
[J]. SOLID STATE IONICS, 1990, 40-1 (pt 2) : 934 - 937
[2] PHASE-TRANSITIONS AND IONIC-CONDUCTIVITY IN BI4V2O11 AN OXIDE WITH A LAYERED STRUCTURE
ABRAHAM, F
DEBREUILLEGRESSE, MF
MAIRESSE, G
NOWOGROCKI, G
[J]. SOLID STATE IONICS, 1988, 28 : 529 - 532
[3] BOIVIN JC, 1991, C SOLID STATE IONICS
[4] ELECTROCHEMICAL CHARACTERIZATION OF BIMEVOX OXIDE-ION CONDUCTORS
IHARADA, T
HAMMOUCHE, A
FOULETIER, J
KLEITZ, M
BOIVIN, JC
MAIRESSE, G
[J]. SOLID STATE IONICS, 1991, 48 (3-4) : 257 - 265
[5] KROG F, 1992, COMMUNICATION SPR
[6] LINHARDT P, 1985, 6TH P INT S MET MAT, P475
[7] Electrical and structural investigations on a new bismuth lead vanadium oxide solid electrolyte
Vannier, R.N.
Mairesse, G.
Nowogrocki, G.
Abraham, F.
Boivin, J.C.
[J]. Solid State Ionics, 1992, 53-56 (pt 2) : 713 - 722
[8] [No title captured]

← 1 →